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tellurium tetrabromide : ウィキペディア英語版
tellurium tetrabromide

Tellurium tetrabromide (TeBr4) is an inorganic chemical compound. It has a similar tetrameric structure to TeCl4.〔''Inorganic Chemistry'',Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 ISBN 0-12-352651-5〕 It can be made by reacting bromine and tellurium. In the vapour TeBr4 dissociates:〔
:TeBr4 TeBr2 + Br2
It is a conductor when molten, dissociating into the ions TeBr3+ and Br
Solutions in benzene and toluene are non conducting and TeBr4 is present as the tetramer, Te4Br16.〔 In solvents with donor properties such as acetonitrile, CH3CN ionic complexes are formed which make the solution conducting:
:TeBr4 + 2CH3CN (CH3CN)2TeBr3+ + Br
==References==



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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